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A sample of [tex]$NO_2$[/tex] at 857.4 K experiences a change in volume from 97.3 L to 83.32 L. If its new pressure is 6.4209 atm at 892.1 K, what was its original pressure in atmospheres?

Answer :

To find the original pressure, we can use the combined gas law, which relates the pressure, volume, and temperature of a gas before and after a change under the same number of moles. The formula for the combined gas law is:

[tex]\[
\frac{P_1 \times V_1}{T_1} = \frac{P_2 \times V_2}{T_2}
\][/tex]

Here, [tex]\( P_1 \)[/tex] is the initial pressure (which we are trying to find), [tex]\( V_1 \)[/tex] is the initial volume, [tex]\( T_1 \)[/tex] is the initial temperature, [tex]\( P_2 \)[/tex] is the final pressure, [tex]\( V_2 \)[/tex] is the final volume, and [tex]\( T_2 \)[/tex] is the final temperature.

Let's plug in the given values:

- [tex]\( V_1 = 97.3 \)[/tex] L
- [tex]\( V_2 = 83.32 \)[/tex] L
- [tex]\( T_1 = 857.4 \)[/tex] K
- [tex]\( T_2 = 892.1 \)[/tex] K
- [tex]\( P_2 = 6.4209 \)[/tex] atm

We need to solve for [tex]\( P_1 \)[/tex]. Rearrange the formula to solve for [tex]\( P_1 \)[/tex]:

[tex]\[
P_1 = \frac{P_2 \times V_2 \times T_1}{V_1 \times T_2}
\][/tex]

Substitute the values into the equation:

[tex]\[
P_1 = \frac{6.4209 \times 83.32 \times 857.4}{97.3 \times 892.1}
\][/tex]

After performing the calculation, we find that:

[tex]\[
P_1 \approx 5.284
\][/tex]

Thus, the original pressure of the gas was approximately 5.284 atm.

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