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It takes 4.0 eV to excite an electron in a box from the ground level to the first excited level. What is the width [tex]L[/tex] of the box?

A. 0.27 mm
B. 0.11 nm
C. 0.53 nm
D. 38.8 nm

Answer :

To solve this problem we will use the concept related to electrons in a box which determines the energy of an electron in that state.

Mathematically this expression is given by,

[tex]E_n= \frac{n^2h^2}{8mL^2}[/tex]

Where,

m = mass of an electron

h = Planck's constant

n = is the integer number of the eigenstate

L = Quantum well width

The change in energy must be given in state 1 and 2, therefore

[tex]\Delta E = E_2 - E_1[/tex]

[tex]\Delta E = \frac{2^2h^2}{8mL^2}-\frac{1^2h^2}{8mL^2}[/tex]

[tex]\Delta E = \frac{3h^2}{8mL^2}[/tex]

Replacing we have:

[tex](4*1.6*10^{-19}) = \frac{3(6.626*10^{34})}{8*(9.11*10^{-31})*L^2}[/tex]

[tex]L = 0.53nm[/tex]

Therefore the correct answer is C.

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Rewritten by : Barada