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The solubility of a compound is 35.6 g/100 mL at 25ºC and 39.1 g/100 mL at 108ºC. If a saturated solution of the compound at 108ºC is allowed to slowly cool to 25ºC, what is the maximum yield of solid crystals that can be obtained?

Answer :

Final answer:

The maximum yield of solid crystals that can be obtained can be calculated by finding the difference between the actual concentration at 108ºC and the equilibrium solubility at 25ºC.

Explanation:

To find the maximum yield of solid crystals that can be obtained, we need to determine the solubility of the compound at 25ºC and compare it to the actual concentration of the compound in the solution at 108ºC. At 25ºC, the solubility is 35.6 g/100 mL, while at 108ºC, it is 39.1 g/100 mL. When the supersaturated solution is cooled to 25ºC, the excess solute will precipitate out until it reaches its equilibrium solubility. The maximum yield of solid crystals will be the difference between the actual concentration at 108ºC and the equilibrium solubility at 25ºC.



Therefore, the maximum yield of solid crystals that can be obtained is 39.1 g/100 mL - 35.6 g/100 mL = 3.5 g/100 mL.

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