High School

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Based on the information in the table, what is [tex]$\Delta H^{\circ}$[/tex] for the reaction [tex]$SO_2(g) + \frac{1}{2}O_2(g) \rightarrow SO_3(g)$[/tex]?

\[
\begin{array}{|l|l|}
\hline
\text{Substance} & \Delta H_f^{\circ} \, (\text{kJ/mol}) \\
\hline
SO_2(g) & -296.1 \\
\hline
SO_3(g) & -395.2 \\
\hline
O_2(g) & 0.0 \\
\hline
\end{array}
\]

A. [tex]-591.3 \, \text{kJ/mol}_{\text{rxn}}[/tex]
B. [tex]-99.1 \, \text{kJ/mol}_{\text{rxn}}[/tex]
C. [tex]+99.1 \, \text{kJ/mol}_{\text{rxn}}[/tex]
D. [tex]+591.3 \, \text{kJ/mol}_{\text{rxn}}[/tex]

Answer :

To find [tex]\(\Delta H^{\circ}\)[/tex] for the reaction [tex]\(SO_2(g) + \frac{1}{2} O_2(g) \rightarrow SO_3(g)\)[/tex], we can use the standard enthalpies of formation ([tex]\(\Delta H_f^{\circ}\)[/tex]) for each substance involved.

Here's how we can calculate it step-by-step:

1. Recall the formula for [tex]\(\Delta H^{\circ}\)[/tex]:
[tex]\[
\Delta H^{\circ} = \sum \Delta H_f^{\circ} (\text{products}) - \sum \Delta H_f^{\circ} (\text{reactants})
\][/tex]

2. Identify the standard enthalpies of formation ([tex]\(\Delta H_f^{\circ}\)[/tex]) from the table:
- For [tex]\(SO_3(g)\)[/tex], [tex]\(\Delta H_f^{\circ} = -395.2 \, \text{kJ/mol}\)[/tex]
- For [tex]\(SO_2(g)\)[/tex], [tex]\(\Delta H_f^{\circ} = -296.1 \, \text{kJ/mol}\)[/tex]
- For [tex]\(O_2(g)\)[/tex], [tex]\(\Delta H_f^{\circ} = 0.0 \, \text{kJ/mol}\)[/tex] (since it's an element in its standard state)

3. Plug these values into the formula:
The products side of the reaction is [tex]\(SO_3(g)\)[/tex], and the reactants side is [tex]\(SO_2(g) + \frac{1}{2} O_2(g)\)[/tex].

[tex]\[
\Delta H^{\circ} = \left[ \Delta H_f^{\circ} (\text{SO}_3) \right] - \left[ \Delta H_f^{\circ} (\text{SO}_2) + \frac{1}{2} \Delta H_f^{\circ} (\text{O}_2) \right]
\][/tex]

[tex]\[
\Delta H^{\circ} = \left[ -395.2 \right] - \left[ -296.1 + 0.5 \times 0.0 \right]
\][/tex]

4. Calculate the [tex]\(\Delta H^{\circ}\)[/tex]:
[tex]\[
\Delta H^{\circ} = -395.2 - (-296.1)
\][/tex]

[tex]\[
\Delta H^{\circ} = -395.2 + 296.1
\][/tex]

[tex]\[
\Delta H^{\circ} = -99.1 \, \text{kJ/mol}
\][/tex]

Based on the calculations, the change in enthalpy for the reaction is [tex]\(-99.1 \, \text{kJ/mol}_{\text{rxn}}\)[/tex].

So, the correct answer is (B) [tex]\(-99.1 \, \text{kJ/mol}_{\text{rxn}}\)[/tex].

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