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Answer :
Final answer:
To calculate the equilibrium constant (Ke) for the reaction between Fe and SCN, you need to first determine the concentrations of Fe and SCN in the equilibrium mixture. The absorbance of the mixture is measured at 447 nm in the spectrophotometer because this wavelength corresponds to the maximum absorption of the FeNCS2⁺ complex.
Explanation:
To calculate the equilibrium constant (Ke) for the reaction between Fe and SCN, you need to first determine the concentrations of Fe and SCN in the equilibrium mixture. From the given information, you can calculate the molar concentrations of Fe and SCN using the volume and molarities provided. Next, use the equation Ke = [FeNCS2⁺] / ([Fe] * [SCN]) to calculate the equilibrium constant.
The absorbance of the mixture is measured at 447 nm in the spectrophotometer because this wavelength corresponds to the maximum absorption of the FeNCS2⁺ complex. By measuring the absorbance, you can indirectly determine the concentration of the FeNCS2⁺ complex, which allows for the calculation of the equilibrium constant.
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