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Which of the following statements regarding Grignard reagents are TRUE?

1. Grignard reagents tend to act as Bronsted acids.
2. Grignard reagents decompose rapidly in anhydrous ether solutions.
3. A Grignard reagent contains nucleophilic carbon.
4. Once prepared, a Grignard reagent should be used quickly.
5. The Grignard reagent is an example of an organometallic compound.

Answer :

Hey there!:

1 - True: Grignard reagents tend to act as Bronsted bases.

2 - False: Grignard reagents decompose rapidly in anhydrous ether solutions

3 - True : A Grignard reagent contains nucleophilic carbon.

4 - False: Once prepared , a Grignard reagent can be easily stored, and need not be used quickly.

5 - True : The Grignard reagent is an example of an organometallic compound.


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Rewritten by : Barada

Final answer:

Grignard reagents do contain a nucleophilic carbon atom, should be used quickly after preparation, and are examples of organometallic compounds. Statements 1 and 2 are false.

Explanation:

The question involves Grignard reagents, which are a type of organometallic compound. Let's address each statement in turn:

  1. Grignard reagents tend to act as Bronsted acids. False. Grignard reagents are not Bronsted acids; instead, they can act as strong bases and nucleophiles because they have a negatively charged carbon atom.
  2. Grignard reagents decompose rapidly in anhydrous ether solutions. False. Anhydrous ether is actually used as a solvent for Grignard reagents because it stabilizes the reagent through solvation.
  3. A Grignard reagent contains nucleophilic carbon. True. The carbon attached to the metal (usually magnesium) in a Grignard reagent has a partial negative charge, making it nucleophilic.
  4. Once prepared, a Grignard reagent should be used quickly. True. Grignard reagents are reactive and can react with atmospheric moisture, so they should be used shortly after preparation.
  5. The Grignard reagent is an example of an organometallic compound. True. Grignard reagents contain carbon-metal bonds, which classifies them as organometallic compounds.

In summary, the correct statements regarding Grignard reagents are 3, 4, and 5.