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Ethanol has \(\Delta H_{vap} = 38.6 \, \text{kJ/mol}\) and \(\Delta S_{vap} = 110 \, \text{J/mol} \cdot \text{K}\). Calculate the boiling point of ethanol in °C.

Answer :

The boiling point of ethanol will be 78.85 °C.

This can be calculated using Clausius-Clapeyron equation, which is:

[tex]ΔHvap / Tb = ΔSvap / R[/tex] ,

where [tex]ΔHvap[/tex] is the heat of vaporization, [tex]ΔSvap[/tex] is the entropy of vaporization, [tex]Tb[/tex] is the boiling point in Kelvin, and [tex]R[/tex] is the gas constant.

Plugging in the values given, we can solve for [tex]Tb[/tex]:

[tex]Tb = ΔHvap / (ΔSvap / R) = (38.6 kJ/mol) / (110 J/mol K) / (8.314 J/mol K)[/tex]

[tex]Tb = 351 K[/tex]

Converting to Celsius:

Tb (°C) = Tb (K) - 273.15 = 351 K - 273.15 = 78.85 °C

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